Reactions oftrans- andcis-Dichlorobis(benzonitrile)platinum(II) with Acetylacetonate and Benzoylacetonate Carbanions. Formation ofN-Acetyl β-Ketoamine Complexes by the Acetyl Group Migration
نویسندگان
چکیده
منابع مشابه
Chiral discrimination in cyclodextrin complexes of amino acid derivatives: β-cyclodextrin/N-acetyl-L- phenylalanine andN-acetyl-D phenylalanine complexes
In a systematic study of molecular recognition of amino acid derivatives in solid-state β-cyclodextrin (β-CD) complexes, we have determined crystal structures for complexes of β-cyclodextrin/N-acetyl-L-phenylalanine at 298 and 20 K and for N-acetyl-D-phenylalanine at 298 K. The crystal structures for the N-acetyl-L-phenylalanine complex present disordered inclusion complexes for which the distr...
متن کاملTheoretical Study on Unimolecular Reactions of Acetyl Cyanide and Acetyl Isocyanide
The potential energy surfaces of acetyl cyanide and its functional isomer acetyl isocyanide in their electronic ground state have been investigated using ab initio molecular orbital MP2(FU)/6-311G** and QCISD(T)/6311G** calculations. The molecular eliminations of CH3COX (X ) CN,NC) to CH3X + CO, HX + CH2CO, and CH2 + HCOX, the unimolecular rearrangements to CH3C-OX and CH3O-CX carbenes, 1,3-hyd...
متن کاملthe past hospitalization and its association with suicide attempts and ideation in patients with mdd and comparison with bmd (depressed type) group
چکیده ندارد.
Reactions of Acetyl Radical with Acetylene – A Computational Study†
Ab initio and DFT molecular orbital calculations predict that acetyl radical reacts with acetylene through interactions primarily involving the SOMO of the radical and the in-plane π-bond of acetylene. An energy barrier (∆E1) of 39.6 kJ mol‒1 is predicted for the preferred anti arrangement of reactants at the CCSD(T)/cc-pVDZ//BHandHLYP/cc-pVDZ level of theory. NBO analysis reveals additional in...
متن کاملFormation of acetyl from succinate by rabbit liver slices.
In the course of a study of the mammalian metabolism of succinate, liver slices derived from rabbits previously given intraperitoneal injections of sodium pantothenate were incubated with succinic acid-l ,4-Cl4 and sulfanilamide (1). Acetylsulfanilamide isolated from the reaction mixture proved to be radioactive, and degradation revealed that all of the Cl* in this product resided in the carbox...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1981
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.54.1077